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Time Dependent Facile Hydrothermal Synthesis of TiO2 Nanorods and their Photoelectrochemical Applications
Shinde DB, Jagadale SK, Mane RK2, Mane RM, Ghanwat VB, Khot KV, Mali SS, Hong CK and Bhosale PN
In the present investigation, we report facile hydrothermal synthesis of TiO2 nanorods with high density rutile phase on Transparent Conducting Oxide (TCO) for enhanced solar cell application. The structural, optical, morphological, compositional and electrochemical properties are investigated by detailed XRD, UV-Vis-NIR spectrophotometer, FESEM, TEM, EDAX, XPS and photoelectrochemical studies. It is demonstrated that, the deposited TiO2 thin film shows pure rutile phase with tetragonal crystal structure. Optical spectra showed strong light absorption in UV region and FESEM images confirm the time dependent growth of TiO2 nanorods. EDAX and XPS Spectra confirm the formation of pure TiO2 nanorods. Photoelectrochemical performance with respect to time dependent growth of TiO2 nanorods showed highest photoconversion efficiency ɳ = 5.1%